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  • 近室溫離子液體電沉積鈦及鈦合金關鍵挑戰與創新策略

    Critical challenges and innovative strategies for electrodeposition of titanium and titanium alloys in near-room-temperature ionic liquids

    • 摘要: 鈦及鈦合金因其優異的比強度、耐腐蝕性等,在航空航天、海洋工程等領域得到了廣泛應用。然而,傳統的鈦及鈦合金制備工藝通常涉及高溫、高能耗、高污染等問題。近室溫電解質體系電沉積技術能顯著降低鈦及鈦合金制備的溫度和能耗,但目前仍存在產物純度不高、電流效率低等問題。為此,本文系統綜述了近室溫體系電沉積鈦及鈦合金的發展歷程,隨后著重分析了近室溫離子液體(ILs)體系電沉積鈦及鈦合金所面臨的核心挑戰,包括電沉積機理復雜、電沉積制備純鈦難和產物品質調控難等關鍵問題。基于此,本文從電沉積機理解析、高效制備純鈦工藝、產物品質調控等多個角度,歸納總結了針對近室溫ILs電沉積鈦及鈦合金的創新優化策略。最后,對該技術未來發展面臨的關鍵挑戰與潛在機遇進行了探討。本文旨在為近室溫ILs電沉積鈦及鈦合金的基礎研究提供有價值的參考,并推動其大規模工業化應用的快速發展。

       

      Abstract: Titanium and its alloys are extensively utilized in aerospace, marine engineering, and various technical industries due to their exceptional specific strength and superior corrosion resistance. Traditional methods of titanium production primarily fall into two categories: metallothermic reduction and molten salt electrolysis. However, both approaches require high-temperature conditions and face systemic challenges, such as stringent material requirements, high energy consumption, and substantial pollutant emissions. These issues pose significant obstacles to the transition of titanium metallurgy toward low-carbon and energy-efficient paradigms. In this context, near-room-temperature electrodeposition has garnered increasing attention as a focus of research for its unique advantages. This technique not only substantially reduces energy consumption and pollution emissions but also simplifies equipment design and operational complexity. Owing to their wide electrochemical windows, low melting points, and high stability, ionic liquids (ILs) have emerged as a pivotal component of this system, attracting considerable research attention. Despite significant advancements in related research in recent years, critical challenges such as low current efficiency and insufficient product purity remain unresolved. Furthermore, there is a notable lack of comprehensive review articles specifically addressing the electrodeposition of titanium and its alloys using ILs at near-room-temperature, particularly those offering systematic analyses of technical challenges and potential optimization pathways. Therefore, in order to further summarize the achievements in related fields, this article first systematically reviews the development of electrodeposition methods for titanium and its alloys in near-room-temperature systems, covering aqueous solutions, organic solvents, and ionic liquids (ILs). Then it focuses on analyzing the key challenges faced by near-room-temperature IL-based systems. First, the complexity of the electrodeposition mechanism is analyzed from two aspects: the complex speciation of titanium in the ionic liquid media and the intricate process of titanium ion electroreduction. Second, the difficulties in achieving deep reduction of titanium ions and achieving high current efficiency are discussed, highlighting the challenges in electrodepositing pure titanium and its alloys. Finally, the article analyzes the causes and manifestations of defects in electrodeposited products in terms of composition and morphology. In addition, this article further comprehensively summarizes the innovative optimization strategies for near-room-temperature ILs electrodeposition of titanium and its alloys, and explores the use of multi-scale theoretical analysis combined with multi-dimensional in-situ experimental characterization to elucidate the electrodeposition mechanism. The paper further outlines strategies for efficient electrodeposition of titanium and its alloys, including the design and development of novel ILs with excellent performance, analysis of electrode processes, and the implementation of corresponding optimization measures, aimed at enabling the deep reduction of titanium ions for electrodeposition of pure titanium and improving current efficiency. An innovative control strategy for electrodeposition products based on multi-parameter and cross-spatiotemporal coupling regulation is also proposed. On this basis, the importance of establishing machine learning models to enable real-time prediction and control is also emphasized. Finally, this article looks forward to the future development challenges and potential opportunities in near-room-temperature ILs electrodeposition of titanium and its alloys. It aims to provide valuable references for fundamental research, to offer theoretical support for technological breakthroughs, and to facilitate the rapid development of large-scale industrial applications.

       

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