Abstract: Vanadium-bearing titanomagnetite concentrates were reduced isothermally by adding pulverized coal and additives.Some factors which influence the metallization degree,such as reaction temperature,reaction time,C-to-Fe molar ratio and additives,were investigated.The enhanced reduction mechanism of additives was also discussed.The results show that reaction temperature,reaction time,C-to-Fe molar ratio and additives have great effect on the metallization degree.Under the condition of the reaction temperature of 1 200℃ and the reaction time of 120 min,the maximum metallization degree is 84.5% without any additive.Using Na₂CO₃ or CaF₂ as an additive,the reduction of vanadium-bearing titanomagnetite concentrates can be promoted.With the addition of 3.0% Na₂CO₃ or CaF₂,the metallization degree of vanadium-bearing titanomagnetite concentrates can reach up to 96.5% and 93.3% after the samples are heated at 1 200℃ for 120 min,respectively.